Tris(pentafluorophenyl)borane-promoted stereoselective glycosylation with glycosyl trichloroacetimidates under mild conditions
| dc.contributor.author | Mishra K.B.; Singh A.K.; Kandasamy J. | |
| dc.date.accessioned | 2025-05-24T09:32:05Z | |
| dc.description.abstract | Tris(pentafluorophenyl)borane-promoted stereoselective glycosylation with trichloroacetimidate glycosyl donors is described. The reactions proceed efficiently with a wide range of acceptors, from sugar to nonsugar, under mild conditions in the presence of a catalytic amount of B(C6F5)3. The perbenzylated glucosyl α-imidate provides β-selective glycosides in 70-92% yields. © 2018 American Chemical Society. | |
| dc.identifier.doi | https://doi.org/10.1021/acs.joc.8b00215 | |
| dc.identifier.uri | http://172.23.0.11:4000/handle/123456789/17743 | |
| dc.relation.ispartofseries | Journal of Organic Chemistry | |
| dc.title | Tris(pentafluorophenyl)borane-promoted stereoselective glycosylation with glycosyl trichloroacetimidates under mild conditions |