Molybdenumhexacarbonyl-Mediated Imino-Carbonylative Acylation of NH-Sulfoximines with Aryl Iodides

Abstract

Development of a catalyst-free, robust and straightforward iminocarbonylation protocol for the synthesis of N-acyl sulfoximines from sulfoximines and aryl iodides in the presence of Mo(CO)6 has been reported. Simple operation, broad substrate scope, wide functional group tolerance and excellent yields are the salient features of this work. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim