Experimental data and modeling for density and viscosity of carbon dioxide (CO2)-loaded and -unloaded aqueous blend of 2-(ethylamino)ethanol (EAE) and aminoethylethanolamine (AEEA) for post-combustion CO2 capture

Abstract

Amine based chemical absorption is the most developed technique for post-combustion CO2 capture from flue gases of low CO2 partial pressure. Density and viscosity data of CO2 – loaded and –unloaded absorbent are important in kinetics study and design the absorption column. Density and viscosity of CO2 loaded and –unloaded aqueous blend of 2-(ethylamino)ethanol (EAE) + aminoethylethanolamine (AEEA) were obtained experimentally in the temperature range of 293.15 to 323.15 K with 5 K temperature interval at atmospheric pressure. Concentration of aqueous EAE + AEEA blend was 10 wt%, 20 wt%, and 30 wt% with 7/3 weight ratio of EAE/AEEA. Excess volume was calculated by using experimental density data and correlated with Redlich-Kister type equation. Correlations were developed to calculate density and viscosity. For CO2-loaded and –unloaded aqueous EAE + AEEA blend, correlations predicted data were with average absolute deviation percentage (AAD %) of 0.1286, 0.0208, respectively for density while with AAD % 4.744, 4.433, respectively for viscosity. Wieland model was also correlated to CO2-loaded viscosity data and AAD % was 2.852 for this model. Moreover, diffusivity of CO2 into the aqueous EAE + AEEA blend was calculated using modified Stokes-Einstein equation. © 2021 Elsevier B.V.