Fenton reaction by H2O2 produced on a magnetically recyclable Ag/CuWO4/NiFe2O4 photocatalyst

Abstract

The development of recyclable H2O2-producing photocatalysts with in situ Fenton-like organic pollutant degradation is currently a topical area of research. This research investigates the visible light photocatalytic formation of H2O2 on Ag/CuWO4/NiFe2O4 composites. Investigations revealed that NiFe2O4 and CuWO4 have staggered valence band (VB) and conduction band (CB) positions, with the former acting as the reduction component. Large-scale molecular dynamics simulations demonstrated that oxygen molecules (in an aqueous medium) have an affinity for the NiFe2O4 surface. Appropriate scavenger experiments and molecular dynamics results point to a Z-scheme mechanism. Substantial H2O2 formation occurred on continuous oxygen-passing through the aqueous reaction medium under visible light irradiation in pure water. This H2O2 successfully degraded tetracycline by an in situ (heterogeneous) Fenton-like reaction. © 2023 The Royal Society of Chemistry.