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Synthesis and computational aspects of Al(ii)-Al(ii) and Ga(ii)-Ga(ii) dihalides based on an amidinate scaffold

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dc.contributor.authorKumar, Arun
dc.contributor.authorBanerjee, Samya
dc.contributor.authorBanerjee, Samya
dc.contributor.authorNazish, Mohd
dc.contributor.authorGraw, Nico
dc.contributor.authorHerbst-Irmer, Regine
dc.contributor.authorStalke, Dietmar
dc.contributor.authorLourderaj, Upakarasamy
dc.contributor.authorRoesky, Herbert W.
dc.date.accessioned2023-04-24T05:49:41Z
dc.date.available2023-04-24T05:49:41Z
dc.date.issued2022-02-28
dc.descriptionThis paper is submitted by the author of IIT (BHU), Varanasien_US
dc.description.abstractAmidinate compounds with stabilized aluminium(ii) and gallium(ii) elements of composition L2M2X2 (3 and 4) have been prepared from their LMX2 (1 and 2) precursor, where M = Al (1 and 4) and Ga (2 and 3); L = PhC(NiPr2C6H3)2 (1 and 4) and PhC(NtBu)2 (2 and 3); and X is I (1 and 4) and Cl (2 and 3) and insights into their bonding are gained. The M-M bond lengths are reported along with the single-crystal X-ray structures of 1-4.en_US
dc.description.sponsorshipHWR thanks the DFG for financial support (RO 224/71-1). NS and UL acknowledge NISER Bhubaneswar for the computational facility. UL also acknowledges the support from SERB, Department of Science and Technology (EMR/2017/004843).en_US
dc.identifier.issn14779226
dc.identifier.urihttps://idr-sdlib.iitbhu.ac.in/handle/123456789/2206
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.relation.ispartofseriesDalton Transactions;Volume 51, Issue 12, Pages 4898 - 4902
dc.subjectAluminum compoundsen_US
dc.subjectScaffoldsen_US
dc.subjectSingle crystalsen_US
dc.subjectAmidinatesen_US
dc.subjectComputational aspectsen_US
dc.subjectDihalidesen_US
dc.subjectSingle crystal x-ray structuresen_US
dc.subjectGallium compoundsen_US
dc.titleSynthesis and computational aspects of Al(ii)-Al(ii) and Ga(ii)-Ga(ii) dihalides based on an amidinate scaffolden_US
dc.typeArticleen_US

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