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Kinetics and thermodynamics of ferrous-ferric equilibrium in sodium aluminoborate glasses
| dc.contributor.author | Pyare R.; Nath P. | |
| dc.date.accessioned | 2025-05-24T09:55:17Z | |
| dc.description.abstract | The oxidation-reduction equilibrium between ferrous and ferric iron in sodium aluminoborate glass melts having molar composition 15Na2O·10Al2O3·75B2O3 has been studied as a function of temperature. The reaction was observed to follow first order kinetics. The energy of activation for the above reaction was calculated. Equations previously suggested to represent the Fe2+-Fe3+ equilibrium were discussed and a new equation is proposed. The enthalpy of the reaction was -8.80 kcal mol-1. © 1984. | |
| dc.identifier.doi | https://doi.org/10.1016/0022-3093(84)90123-6 | |
| dc.identifier.uri | http://172.23.0.11:4000/handle/123456789/19710 | |
| dc.relation.ispartofseries | Journal of Non-Crystalline Solids | |
| dc.title | Kinetics and thermodynamics of ferrous-ferric equilibrium in sodium aluminoborate glasses |