Hydrogenation of (Zr69.5Al7.5Cu12Ni 11)100 - XTix quasicrystalline alloys and its effect on their structural and microhardness behavior

Abstract

The present study deals with the microstructural changes with respect to the addition of Ti and their correlation with hydrogen storage characteristics of (Zr69.5Al7.5Cu12Ni11) 100 - xTix (x = 0, 4 and 12) quasicrystalline alloys. The grain size of quasicrystals decreases with addition of Ti. It has been found that the alloy with x = 0 absorbed 1.20 wt. %, whereas the alloys with x = 4 and 12 absorbed 1.38 wt. % and 1.56 wt. % of hydrogen respectively. Hydrogenation was found to exhibit a significant effect on the structure/microstructure and microhardness behavior of (Zr69.5Al7.5Cu 12Ni11)100 - xTix quasicrystalline alloys. Variation in the microhardness behavior has been discussed based on a structure-property correlation. © 2013 Elsevier B.V.