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Superior electrocatalytic hydrogen evolution activity of a triply bridged diruthenium(ii) complex on a carbon cloth support
| dc.contributor.author | Arya Y.; Ansari T.; Bera S.K.; Panda S.; Indra A.; Lahiri G.K. | |
| dc.date.accessioned | 2025-05-23T11:13:28Z | |
| dc.description.abstract | This article describes the structural authentication of a unique triply bridged [1](ClO4)2 and monomeric [2]ClO4/[3]ClO4. Electrochemical HER on a carbon cloth support demonstrated the superior performance of [1](ClO4)2 with high TON (>105) and its long-term stability. The primary kinetic isotope effect of [1](ClO4)2 revealed the involvement of PCET in the rate-determining step. © 2024 The Royal Society of Chemistry. | |
| dc.identifier.doi | https://doi.org/10.1039/d4cc01173b | |
| dc.identifier.uri | http://172.23.0.11:4000/handle/123456789/5864 | |
| dc.relation.ispartofseries | Chemical Communications | |
| dc.title | Superior electrocatalytic hydrogen evolution activity of a triply bridged diruthenium(ii) complex on a carbon cloth support |