Cationic complexes of chelated bis(η-cyclopentadienyl)titanium(IV) with halometallates of gallium(III), indium(III) and thallium(III)

Abstract

Eight complexes of the chelated bis(η-cyclopenta-dienyl)titanium(IV) cation. [η-Cp2TiL][MX4] (L = acetyl-acetone, M = GaIII, InIII or TiIII: X = Cl, Br or I) have been isolated from aqueous solution and characterised by elemental analyses and i.r. data. Their ionic nature has been confirmed by conductance measurements. © 1980 Verlag Chemie, GmbH.