Effect of zirconia on densification and properties of natural Indian magnesite

Abstract

Indian magnesite mineral has substantial amount of impurities like CaO, SiO2 & Fe2O3. During sintering at elevated temperature these impurities react to form low melting phases like monticellite (CMS), which can degrade the high temperature properties of magnesite. In the present study, ZrO2 was added to reduce the formation of low melting phase in order to improve the hot strength. Amount of additive was varied between 2 and 6 wt.% with respect to raw magnesite. It was observed that addition of ZrO2 reduces the formation of low melting CMS at higher temperature and improves the flexural strength at 1200 °C. Periclase grain shape also changed from rounded to subrounded in the presence of zirconia. © 2015 Elsevier B.V. All rights reserved.